Phase relations in the Tl₂SnSe₃–Tl₄SnSe₄–TlBiSe₂ quasiternary system

Chem. Met. Alloys 4 (2011) 94-97

https://doi.org/10.30970/cma4.0156

A.A. Kozma, I.E. Barchiy, E.Yu. Peresh

The quasiternary system Tl₂SnSe₃–Tl₄SnSe₄–TlBiSe₂ was investigated by DTA and X-ray diffraction in combination with mathematical modeling. Perspective views of the phase interactions and a projection of the liquidus surface were constructed. No quaternary compounds were observed. The system is of the invariant eutectic type. The three-dimensional one-, two- and three-phase regions present in the Tl₂SnSe₃–Tl₄SnSe₄–TlBiSe₂ system are described.

Liquidus projection of the Tl₂SnSe₃–Tl₄SnSe₄–TlBiSe₂ system

Keywords

Phase diagram / Thermal analysis / X-ray diffraction