X-ray fluorescence
determination of the composition of ash from incineration of organochlorine wastes from direct chlorination of ethylene
to 1,2-dichloroethane
Chem.
Met. Alloys 13 (2020)
23-28
https://doi.org/10.30970/cma13.0401
Ihor
POLIUZHYN, Vitalii STADNIK, Stepan
KOLOBYCH, Ruslana HUMINILOVYCH, Pavlo SHAPOVAL
Ash forms during the
thermal utilization of organochlorine wastes from the
direct chlorination of ethylene to 1,2-dichloroethane
in the production of vinyl chloride. The composition of ash collected at Karpatnaftochim Ltd. was determined by X-ray fluorescence
spectrometry. The ash macrocomponents are Fe2O3
and FeCl3, as well as magnesium and sodium chlorides. Based on the
results of the determination of the ash macro composition, ways were proposed
to solve technological problems of organochlorine
waste utilization.
Correlation between the results of
the XRF method and the calculation method.
Keywords
Organochlorine
by-products / X-ray fluorescence spectrometry / Ash from organic waste
incineration