СИСТЕМА Ho–Ni–In ПРИ 870 K

V. Zaremba, M. Dzevenko, G. Nychyporuk, Yu. Maletska, Ya. Kalychak

Анотація


Досліджено взаємодію компонентів і побудовано ізотермічний переріз діаграми стану системи Ho–Ni–In у повному концентраційному інтервалі при 870 K. За температури відпалу в системі існує 12 тернарних сполук. Тернарна сполука HoNi1,00-0,50In1,00-1,50 має область гомогенності вздовж ізоконцентрати 0,333 ат. частки гольмію, а між сполуками HoNi2 та HoNi4In утворюється неперервний ряд твердих розчинів. На основі сполуки NiIn формується твердий розчин включення-віднімання складу Ho0-0,08NiIn1-0,94.


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Kalychak Ya. M., Zaremba V. I., Pöttgen R., Lukachuk M., Hoffmann R.-D. Rare Earth–Transition Metal–Indides // In: K. A. Gschneidner, Jr., J.-C. Bünzli, V. K. Pecharsky (eds.), Handbook on the Physics and Chemistry of Rare Earths. Elsevier. Amsterdam, 2005. Vol. 34. P. 1–133. DOI: https://doi.org/10.1016/S0168-1273(04)34001-8

Villars P., Cenzual K. (Eds.). Pearson’s Crystal Data – Crystal Structure Database for Inorganic Compounds. Release 2019/2020, ASM International, Materials Park. 2019.

Petrovic C., Pagliuso P. G., Hundley M. F., Movshovich R., Sarrao J. L., Thompson J. D., Fisk Z., Monthoux P. Heavy-fermion super-conductivity in CeCoIn5 at 2.3 K // J. Physics: Condensed Matter. 2001. Vol. 13. P. L337–L342. DOI: http://dx.doi.org/10.1088/0953-8984/13/17/103

Chen G., Ohara S., Hedo M., Uwatoko Y., Sakamoto I. Transport properties of the heavy-fermion superconductor Ce2CoIn8 // J. Physics: Condensed Matter. 2003. Vol. 15. P. S2175–S2178. DOI: https://doi.org/10.1088/0953-8984/15/28/346

Zhang H., Xu Z. Y., Zheng X. Q., Shen J., Hu F. X., Sun J. R., Shen B. G. Magnetocaloric effects in RNiIn (R = Gd–Er) intermetallic compounds // J. Appl. Phys. 2011. Vol. 109. P. 123926–1–6. DOI: https://doi.org/10.1063/1.3603044

Tyvanchuk Yu. B., Kalychak Ya. M., Gondek Ł., Rams M., Szytuła A., Tomkowicz Z. Magnetic properties of RNi1-xIn1+x (R = Ho–Er) compounds // J. Magn. Magn. Mater. 2004. Vol. 277. P. 368–378. DOI: https://doi.org/10.1016/j.jmmm.2003.11.018

Kalychak Ya. Phase equilibria and crystal structures of compounds in R–Cu–In systems // Izv. RAN. Metally. 1998. No. 4. P. 110118 (in Russian).

Kalychak Ya. The Ce–Co–In system // Visnyk Lviv Univ. Ser. Chem. 1999. Iss. 38. P. 70–73 (in Ukrainian).

Dzevenko M., Hamyk A., Tyvanchuk Yu., Kalychak Ya. Phase equlibria in the Er–Co–In system and crystal structure of Er8CoIn3 compound // Cent. Eur. J. Chem. 2013. Vol. 11, Nо. 4. P. 604–609. DOI: https://doi.org/10.2478/s11532-012-0195-Ho

Gabay A. M., Hadjipanayis G. C. Phases and phase equilibria in cobalt-rich Pr–Co–In alloys for permanent magnets // J. Alloys. Compd. 2010. Vol. 500. P. 161–166. DOI: https://doi.org/10.1016/j.jallcom.2010.03.247

Demchyna M., Belan B., Manyako M., Akselrud L., Gagor A., Dzevenko M., Kalychak Y. Phase equilibria in the Dy–Fe–In system and crystal structure of Dy6Fe1.72In // Intermetallics. 2013. Vol. 37. P. 22–26. DOI: http://dx.doi.org/10.1016/j.intermet.2013.01.010

Bigun I., Demchyna M., Dzevenko M., Belan B., Manyako M., Tyvanchuk Yu., Kalychak Ya. The component interaction in {Gd, Tb}–Fe–In systems // Visnyk Lviv Univ. Ser. Chem. 2013. Iss. 54, Pt. 1. P. 3–10 (in Ukrainian).

Kalychak Ya. The component interaction in Ce–Ni–In system // Ukr. Chem. Jorn. 1998. Vol. 64, No. 7. P. 15–20 (in Ukrainian).

Zaremba V., Dzevenko M., Pöttgen R., Kalychak Ya. Phase equilibrium in the
Gd–Ni–In system at T = 870 K // Z. Naturforsch. B. 2019. Vol. 74(7–8). P. 613–618. DOI: https://doi.org/10.1515/znb-2019-0083

Dzevenko M., Tyvanchuk Yu., Demidova Ch., Lukachuk M., Kalychak Ya. Phase equilibria in Tb–Ni–In system at 870 K // Visnyk Lviv Univ. Ser. Chem. 2014. Iss. 55, Pt. 1. P. 21–28 (in Ukrainian).

Tyvanchuk Yu. B., Zaremba V. I., Akselrud L. G., Szytula A., Kalychak Ya. M. The Dy–Ni–In system at 870 K: isothermal section, solid solutions, crystal structures // J. Alloys Compd. 2017. Vol. 704. P. 717–723. DOI: http://dx.doi.org/10.1016/j.jallcom.2017.02.023

Dzevenko M., Tyvanchuk Yu., Bratash L., Zaremba V., Havela L., Kalychak Ya. Ternary system Er–Ni–In at T = 870 K // J. Solid State Chem. 2011. Vol. 184, Iss. 10. P. 2707–2712. DOI: https://doi.org/10.1016/j.jssc.2011.08.006

Tyvanchuk Yu. B., Lukachuk M., Pöttgen R., Szytula A., Kalychak Ya. M. The ternary system Tm–Ni–In at 870 K // Z. Naturforsch. B: J. Chem. Sci. 2015. Vol. 70. P. 665–670. DOI: https://doi.org/10.1515/znb-2015-0075

Zaremba V., Dzevenko M., Nychyporuk G., Kalychak Ya. Phase equilibrium in the system Y–Ni–In at 870 K // Visnyk Lviv Univ. Ser. Chem. 2021. Iss. 62. P. 18–27 (in Ukrainian). DOI: http://dx.doi.org/10.30970/vch.6201.018

Villars P., Okamoto H., Cenzual K. (Eds.) ASM Alloy Phase Diagram Database. Release 2006/2018, ASM International, Materials Park, OH. 2018.

Phase diagrams of binary nickel alloys / P. Nash, editor. Materials Park, OH: ASM International. 1991. 394 p.

Okamoto H. In–Ni (Indium–Nickel) // J. Phase Equilibria. 1999. Vol. 20, No. 5. P. 540. DOI: https://doi.org/10.1361/105497103770330479

Kraus W., Nolze G. Powder Cell For Windows. Berlin, 1999.

STOE WinXPOW, Version 1.2, STOE & CIE GmbH. Darmstadt, 2001.

Rodriguez-Carvajal J. Recent developments of the program FULLPROF // Commission on Powder Diffraction. Newsletter. 2001. Vol. 26. P. 12–19.

Bigun I., Dzevenko M., Havela L., Kalychak Ya. RENi9In2 (RE = Rare-Earth Metal): Crystal Chemistry, Hydrogen Absorption, and Magnetic Properties // Eur. J. Inorg. Chem. 2014. Iss.16. P. 2631–2642. DOI: https://doi.org/10.1002/ejic.201400058

Kalychak Y. M., Akselrud L. G., Zaremba V. I., Baranyak V. M. The crystal structure of the RNi9In2 (R = Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er) compounds // Dopov. Akad. Nauk Ukr. RSR. Ser. B. 1984. No. 8. P. 35–37 (in Ukrainian).

Tyvanchuk Y. B., Svitlyk V. O., Kalychak Y. M. The crystal structure of Ho4Ni11In20 // Cent. Eur. J. Chem. 2012. Vol. 10. P. 354–359. DOI: https://doi.org/10.2478/s11532-011-0146-z

Zaremba V. I., Baranyak V. M., Kalychak Y. M. Crystal structure of the RNi4In compounds // Visnyk Lviv Univ. Ser. Chem. 1984. Iss. 25. P. 18–19 (in Russian).

Zaremba V. I., Belskii V. K., Kalychak Y. M., Pecharskii V. K., Gladyshevskii E. I. The crystal structure of the R10Ni9In20 (R = Ho, Er, Tm, Lu) compounds // Dopov. Akad. Nauk Ukr. RSR. Ser. B. 1987. No. 3. P. 42–45 (in Ukrainian).

Ferro R., Marazza R., Rambaldi G. Equiatomic ternary phases in the alloys of the rare earths with indium and nickel or palladium // Z. Metallkd. 1974. No. 65. P. 37–39. DOI: https://doi.org/10.1515/ijmr-1974-650106

Kalychak Ya. M., Zaremba V. I., Tyvanchuk Yu. B. The solid solutions with ZrNiAl structure type in the R–Ni–In systems // Coll. Abs. Sixth International conference on crystal chemistry of intermetallic compounds. Lviv, 1995. P. 77.

Gondek L., Szytula A., Baran S., Rams M., Hernandez Velasco J., Tyvanchuk Y. B. Magentic structures of non-stoichiometric hexagonal RNi1-xIn1+x (R = Dy, Ho, Er) compounds // J. Magn. Magn. Mater. 2004. No. 278. P. 392–396.

Zaremba V. I., Bruskov V. A., Zavalii P. Y., Kalychak Y. M. Crystal structure of R2Ni2In compounds (R = Y, Sm, Gd, Tb, Ho, Er, Tm, Lu) // Izv. Akad. Nauk SSSR. Neorg. Mater. 1988. Vol. 24. P. 409–411 (in Russian).

Kalychak Y. M., Zaremba V. I., Baranyak V. M., Zavalii P. Y., Bruskov V. A., Sysa L. V., Dmytrakh O. V. Crystal structure of the compounds R2Ni2In, R2Ni2-xIn and R2Cu2In (R = La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Lu, Y) // Izv. Akad. Nauk SSSR. Neorg. Mater. 1990. Vol. 26. P. 94–96 (in Russian).

Tyvanchuk Y. B., Baran S., Jaworska Gołab T., Duraj R., Kalychak Y. M., Szytuła A. Structural chemistry and magnetic properties of R2Ni2-xIn (R = Gd–Er, x = 0.22 or 0.3) compounds // Acta Phys. Pol. A. 2012. Vol. 121. P. 678–681.

Zaremba V. I., Kalychak Y. M., Zavalii P. Y., Bruskov V. A. Crystal structures of the compounds R5Ni2In4 (R = Ho, Er, Tm, Lu) // Kristallografiya. 1991. Vol. 36. P. 1415–1418 (in Russian).

Tyvanchuk Y. B., Penc B., Szytula A., Zarzycki A. Magnetic Properties of Ho5Ni2In4 // Acta Phys. Pol. A. 2010. No. 117. P. 599–600.

Ritter C., Provino A., Manfrinetti P., Pecharsky V. K., Gschneidner K. A. Jr., Dhar S. K. Magnetic structures of R5Ni2In4 and R11Ni4In9 (R = Tb and Ho): Strong hierarchy in the temperature dependence of the magnetic ordering in the multiple rare-earth sublattices // J. Phys.: Condens. Matter. 2015. Vol. 27. P. 476001–1–20. DOI: https://doi.org/10.1088/0953-8984/27/47/47600

Galadzhun Y., Dzevenko M., Zaremba V., Stepien-Damm J., Kalychak Y. RE6Ni2In (RE = Gd, Tb, Dy, Ho, Lu) – the new representatives of Ho6Co2Ga structure type // Acta Cryst. 2005. Vol. A61. P. 372.

Lukachuk M., Galadzhun Y. V., Zaremba R. I., Kalychak Y. M., Zaremba V. I., Rodewald U. Ch., Pöttgen R. New rare earth metal-rich indides RE14Ni3In3 (RE = Sc, Y, Ho–Tm, Lu) – synthesis and crystal chemistry // J. Solid State Chem. 2005. Vol. 178. P. 2724–2733. DOI: https://doi.org/10.1016/j.jssc.2005.06.021

Heying B., Niehaus O., Rodewald U. Ch., Pöttgen R. Indides RE3T2In4 (RE = Y, Gd–Tm, Lu; T = Ni, Ru, Rh) with a ZrNiAl superstructure // Z. Naturforsch. 2016. Vol. 71(12). P. 1261–1267. DOI: https://doi.org/10.1515/znb-2016-0167

Mansey R. C., Rainor G. V., Harris I. R. Rare-earth intermediate phases. V. The cubic Laves phases formed by rare-earth metals with iron and nickel // J. Less-Common Met. 1968. Vol.14. P. 329–336. DOI: https://doi.org/10.1016/0022-5088(68)90038-6

Hellner E. Das System Nickel–Indium // Z. Metallkd. 1950. No. 41. P. 401–406.

Kalychak Y. M., Bakar A. M. The systems Ho–Cu–In and Er–Cu–In // Visnyk Lviv Univ. Ser. Chem. 1994. Iss. 33. P. 32–36 (in Ukrainian).




DOI: http://dx.doi.org/10.30970/vch.6301.016

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