ВОЛЬТАМПЕРОМЕТРИЧНЕ ВИЗНАЧЕННЯ ІРИДІЮ(IV) З ВИКОРИСТАННЯМ 5-ГІДРОКСИІМІНО-4-ІМІНО-1,3-ТІАЗОЛІДИН-2-ОНУ

P. Rydchuk, О. Tymoshuk, L. Oleksiv, I. Patsai

Анотація


Показано, що наявність 5-гідроксиіміно-4-іміно-1,3-тіазолідин-2-ону в розчинах Ir(IV) спричиняє значне зростання піка каталітичних струмів водню (КСВ). Визначено оптимальні умови та розроблено методику вольтамперометричного визначення Ir(IV) за піком КСВ з використанням азолідонового похідного 5-гідроксиіміно-4-іміно-1,3-тіазолідин-2-ону. Запропонована методика характеризуєть­ся хорошою чутливістю (LOD = 1,7×10-7 М), інтервал визначуваних концентрацій становить один концентраційний порядок. Досліджено селективність методики щодо йонів супутніх металів.

 

Ключові слова: іридій, вольтамперометричне визначення, азолідон, оксим.


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DOI: http://dx.doi.org/10.30970/vch.6201.145

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