СИСТЕМИ TbNiIn1-xMx (M = Al, Ge, Sb)
Анотація
Взаємодію компонентів у системах TbNiIn1-xMx(M = Al, Ge, Sb) досліджено рентгенівським фазовим та EDX аналізами у повному концентраційному інтервалі при 873 K. Визначено характер розчинності четвертого компонента у вихідних сполуках, межі твердих розчинів та уточнено параметри елементарних комірок. Методом монокристала уточнено кристалічну структуру сполуки TbNiIn0,28Al0,72: структурний тип ZrNiAl, просторова група P-62m, a = 0,71452(6), c = 0,38394(3) нм, R1 = 0,0152, 307 відбить hkl, 15 уточнюваних параметрів. Обговорено результати взаємодії компонентів у досліджених системах.
Ключові слова: Індій, твердий розчин, метод порошку, метод монокристала, кристалічна структура.
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DOI: http://dx.doi.org/10.30970/vch.6101.052
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